基于函数系数自回归模型的风速时间序列预测

准确预测风电场风速是解决风能对电力系统所造成的安全、稳定运行和电能质量等问题的有效途径之一.风速的难以预测是由于它的高度随机和非线性.基于一种非参数的非线性自回归随机模型来预测风速,模型的自回归系数随模型依赖变量的变化而变化,因而它有灵活的非线性结构.数值实验和比较结果表明了这种函数系数自回归模型在风电场风速预测中的有效性.     

Suppression of ringing oscillations from high speed rubber compression curves through a detailed modal characterization of servo-hydraulic machines

System ringing is one of the most important factors affecting the quality of data obtained in high speed dynamic material tests using servo-hydraulic machines. This phenomenon is characterized by vibrations originated by the excitation of predominant modes of the machine during tests, producing distinctive waves in material curves that severely distort the required results. In the specialized literature, the quantitative study of these vibrations has mainly been carried out considering the testing machine as a single degree of freedom system, which has led to a general understanding of the variables involved in the process. However, discrepancies between analytical predictions and experimental observations have been detected using the single degree of freedom approach, so the need for further detailed study of machine dynamic characteristics has been reported. The work presented in this paper addresses this requirement by means of a detailed characterization of the dynamic behavior of a MTS 819.10 high rate testing system. Natural frequencies, mode shapes and damping factors have been obtained from an experimental modal analysis performed on the machine and a mathematical model of the process has been developed from these modal parameters. This model has been used to detect the modes that have the greatest influence in system ringing when testing rubber at high strain rates, and to predict quantitatively the amplitudes of vibrations produced in the process. Material curves have been corrected by subtracting the predicted undulations from the original measurements, obtaining smooth curves that adequately reflect the real material behavior at high strain rates and, thus, demonstrating the effectiveness of the proposed procedure. Although the research conducted in this work has been focused on rubber, the procedure can be extended equally to characterize other materials, thus constituting a valuable tool to correct experimental measurements contaminated by ringing.     

Separation and purification of two taxanes and one xylosyl‐containing taxane from Taxus wallichiana Zucc.: A comparison between high‐speed countercurrent chromatography and reversed‐phase flash chromatography

10‐Deacetylbaccatin III, an important semisynthetic precursor of paclitaxel and docetaxel, can be extracted from Taxus wallichiana Zucc. A process for the isolation and purification of 10‐deacetylbaccatin III ( 1 ), baccatin III ( 2 ), and 7β‐xylosyl‐10‐deacetyltaxol ( 3 ) from the leaves and branches of Taxus wallichiana Zucc. via macroporous resin column chromatography combined with high‐speed countercurrent chromatography or reversed‐phase flash chromatography was developed in this study. After fractionation by macroporous resin column chromatography, 80% methanol fraction was selected based on high‐performance liquid chromatography and liquid chromatography with mass spectrometry qualitative analysis. A solvent system composed of n‐hexane, ethyl acetate, methanol, and water (1.6:2.5:1.6:2.5, v/v/v/v) was used for the high‐speed countercurrent chromatography separation at a flow rate of 2.5 mL/min. The reversed‐phase flash chromatography separation was performed using methanol/water as the mobile phase at a flow rate of 3 mL/min. The high‐speed countercurrent chromatography separation produced compounds 1 (10.2 mg, 94.4%), 2 (2.1 mg, 98.0%), and 3 (4.6 mg, 98.8%) from 100 mg of sample within 110 min, while the reversed‐phase flash chromatography separation purified compounds 1 (9.8 mg, 95.6%) and 3 (4.9 mg, 97.9%) from 100 mg of sample within 120 min.     

Separation and purification of two minor typical diarrhetic shellfish poisoning toxins from harmful marine microalgae via combined liquid chromatography with mass spectrometric detection

A novel method was developed for the purification of two typical diarrhetic shellfish poisoning toxins from toxin‐producing marine microalgae using macroporous resin, high‐speed countercurrent chromatography–mass spectrometry, and semipreparative high‐performance liquid chromatography–mass spectrometry. Analytical high‐performance liquid chromatography–mass spectrometry was used for identification and purity analysis of okadaic acid and dinophysistoxin‐1 because they exhibit no visible or ultraviolet absorption. First, four kinds of macroporous resins were investigated, and HP‐20 macroporous resin was selected for the preenrichment and cleanup of the two target toxins. Second, the resin‐purified sample was further purified using high‐speed countercurrent chromatography coupled with a mass spectrometer. The purities of the obtained okadaic acid and dinophysistoxin‐1 were 89.0 and 83.0%, respectively, as determined through analytical high‐performance liquid chromatography–mass spectrometry. Finally, further purification was carried out using semipreparative high‐performance liquid chromatography with mass spectrometry, and the purities of the final okadaic acid and dinophysistoxin‐1 products were both over 98.0% based on the analytical high‐performance liquid chromatography–mass spectrometry chromatograms and fraction spectra. This work demonstrates that the proposed purification process is a powerful method for the preparation of high‐purity okadaic acid and dinophysistoxin‐1 from toxin‐producing marine microalgae. Moreover, it is particularly important for the purification and preparation of minor toxins that exhibit no visible or ultraviolet absorption from harmful marine algae.     

A Complex Mode Method for Wind-Induced Responses of 6-Parameter Practical Viscoelastic Damping Energy Dissipation Structures Based on the Davenport Wind Speed Spectrum北大核心CSCD

针对六参数实用黏弹性阻尼耗能结构,基于Davenport风速谱系列响应问题进行了系统的研究.首先,利用六参数黏弹性阻尼器的微分型本构关系,建立了耗能结构基于Davenport风速谱激励下的运动方程;然后,运用复模态法将耗能结构的运动方程由二阶微分方程转化为一阶方程,获得了耗能结构系统对风振激励响应的频域解和功率谱密度函数表达式;最后,利用数学恒等式,基于随机振动理论获得了耗能结构系统在Davenport风速谱激励下的响应和阻尼器受力的解析解.该文方法不仅考虑了结构系统在风振激励作用下全振型展开的结果,表达式较现有结果更为简便,效率及精度更高,且适用于非经典阻尼结构.     

基于等效密度流体模型的地声参数分析

目前的地声参数反演多采用液态海底模型,但是实际海底为多孔弹性海底。该文在等效密度流体模型基础上,通过计算液态海底和多孔弹性海底的反射系数及传播损失,给出了等效密度流体模型和液态海底模型的等效性分析。数值仿真结果表明在低频情况下,多孔弹性海底给出的快纵波声速与等效密度流体模型给出的声速以及等效密度流体的实部与真实的海底密度基本一致。将等效密度流体模型近似看作液态海底模型进行反射系数和传播损失计算,在小掠射角和远距离时,计算结果表明与多孔弹性海底计算结果具有较好一致性,从而以此为依据确定海底为液态,进行地声参数反演。     

深海低声速沉积层简正波用于海底参数反演*

现有深海地声参数反演研究通常基于全波场理论,存在计算量大、多值性以及需要准确的水文环境信息等问题。针对这一问题,提出一种基于简正波频散特征的深海低声速沉积层海底参数反演方法。在南海北部大陆坡海域的一次实验中,坐底式水听器(深度约1740 m)接收的沉底弹信号中观察到一种低频成分先到而高频成分后至的到达结构,由被限制在低声速沉积层的简正波组成。通过匹配沉积层简正波60-220 Hz频段内的到达时间差对实验海域的低声速海底参数进行反演,得到沉积层厚度为16.4 m,沉积层声速为1450.5 m/s,与底质采样数据比较吻合,且具有较高的可信度,验证了所提方法的有效性。由于沉积层密度对简正波频散特征的敏感性较差,其反演结果可信度不是很高,需要进一步研究。     

The Peculiar Dynamics of Cavitation Bubbles

Details from cavitation bubble dynamics are reported: jet formation, counterjet formation, shock wave radiation and light emission. Multiple shock wave radiation from single bubble collapse with jet formation could be time resolved by high speed photography with 20 million frames per second. An explanation of counterjet formation is given. Pictures of the light emission (sonoluminescence) in acoustic cavitation are presented.     

Sudden Blocking of a Supercritical Open‐Channel Flow

This paper reports results of experiments in which a steadystate nonuniform supercritical openchannel flow was suddenly blocked by a rapidly falling gate at a downstream distance of about one hundred critical depths. This results in a hydraulic jump propagating upstream. Experimental data on the shape, height, and propagation speed of its leading front are given. It is shown that the parameters of the jump differ significantly from the values found using a quasistationary approach.     

TiB2增强Al2O3陶瓷刀具高速干切削摩擦磨损性能

采用TiB2增强Al2O3陶瓷刀具对淬硬钢进行高速干切削试验,利用切削高温作用下的摩擦化学反应,在刀具表面原位生成具有润滑作用的反应膜,从而实现Al2O3/TiB2陶瓷刀具的自润滑.结果表明:低速干切削时,Al2O3/TiB2陶瓷刀具的磨损机制主要表现为粘着磨损和磨料磨损;而在高速干切削时,刀具的磨损机制主要表现为氧化磨损,刀具表面经由氧化反应生成具有润滑作用的反应膜而起到固体润滑作用,从而使刀具的耐磨性能提高,随着TiB2含量和切削速度的增加,反应膜的减摩抗磨作用增强;而在切削区通入氮气时,由于刀具表面氧化膜形成受阻,刀具的抗磨能力有所降低.